Aqui está um exemplo para configurar certificados SSL para o MySQL:

DIR=`pwd`/openssl
PRIV=$DIR/private

mkdir $DIR $PRIV $DIR/newcerts
cp /usr/share/ssl/openssl.cnf $DIR
replace ./demoCA $DIR -- $DIR/openssl.cnf

# Crie os aarquivos necessário: $database, $serial e o diretório
$new_certs_dir (opcional)

touch $DIR/index.txt
echo "01" > $DIR/serial

#
# Geração do Certificate Authority(CA)
#

openssl req -new -x509 -keyout $PRIV/cakey.pem -out $DIR/cacert.pem \
    -config $DIR/openssl.cnf

# Saída exemplo:
# Using configuration from /home/monty/openssl/openssl.cnf
# Generating a 1024 bit RSA private key
# ................++++++
# .........++++++
# writing new private key to '/home/monty/openssl/private/cakey.pem'
# Enter PEM pass phrase:
# Verifying password - Enter PEM pass phrase:
# -----
# You are about to be asked to enter information that will be incorporated
# into your certificate request.
# What you are about to enter is what is called a Distinguished Name or a DN.
# There are quite a few fields but you can leave some blank
# For some fields there will be a default value,
# If you enter '.', the field will be left blank.
# -----
# Country Name (2 letter code) [AU]:FI
# State or Province Name (full name) [Some-State]:.
# Locality Name (eg, city) []:
# Organization Name (eg, company) [Internet Widgits Pty Ltd]:MySQL AB
# Organizational Unit Name (eg, section) []:
# Common Name (eg, YOUR name) []:MySQL admin
# Email Address []:

#
# Create server request and key
#
openssl req -new -keyout $DIR/server-key.pem -out \
    $DIR/server-req.pem -days 3600 -config $DIR/openssl.cnf

# Saída exemplo:
# Using configuration from /home/monty/openssl/openssl.cnf
# Generating a 1024 bit RSA private key
# ..++++++
# ..........++++++
# writing new private key to '/home/monty/openssl/server-key.pem'
# Enter PEM pass phrase:
# Verifying password - Enter PEM pass phrase:
# -----
# You are about to be asked to enter information that will be incorporated
# into your certificate request.
# What you are about to enter is what is called a Distinguished Name or a DN.
# There are quite a few fields but you can leave some blank
# For some fields there will be a default value,
# If you enter '.', the field will be left blank.
# -----
# Country Name (2 letter code) [AU]:FI
# State or Province Name (full name) [Some-State]:.
# Locality Name (eg, city) []:
# Organization Name (eg, company) [Internet Widgits Pty Ltd]:MySQL AB
# Organizational Unit Name (eg, section) []:
# Common Name (eg, YOUR name) []:MySQL server
# Email Address []:
#
# Please enter the following 'extra' attributes
# to be sent with your certificate request
# A challenge password []:
# An optional company name []:

#
# Remove the passphrase from the key (optional)
#

openssl rsa -in $DIR/server-key.pem -out $DIR/server-key.pem

#
# Assina o certificado do servidor
#
openssl ca  -policy policy_anything -out $DIR/server-cert.pem \
    -config $DIR/openssl.cnf -infiles $DIR/server-req.pem

# Saída exemplo:
# Using configuration from /home/monty/openssl/openssl.cnf
# Enter PEM pass phrase:
# Check that the request matches the signature
# Signature ok
# The Subjects Distinguished Name is as follows
# countryName           :PRINTABLE:'FI'
# organizationName      :PRINTABLE:'MySQL AB'
# commonName            :PRINTABLE:'MySQL admin'
# Certificate is to be certified until Sep 13 14:22:46 2003 GMT (365 days)
# Sign the certificate? [y/n]:y
#
#
# 1 out of 1 certificate requests certified, commit? [y/n]y
# Write out database with 1 new entries
# Data Base Updated

#
# Create client request and key
#
openssl req -new -keyout $DIR/client-key.pem -out \
    $DIR/client-req.pem -days 3600 -config $DIR/openssl.cnf

# Saída exemplo:
# Using configuration from /home/monty/openssl/openssl.cnf
# Generating a 1024 bit RSA private key
# .....................................++++++
# .............................................++++++
# writing new private key to '/home/monty/openssl/client-key.pem'
# Enter PEM pass phrase:
# Verifying password - Enter PEM pass phrase:
# -----
# You are about to be asked to enter information that will be incorporated
# into your certificate request.
# What you are about to enter is what is called a Distinguished Name or a DN.
# There are quite a few fields but you can leave some blank
# For some fields there will be a default value,
# If you enter '.', the field will be left blank.
# -----
# Country Name (2 letter code) [AU]:FI
# State or Province Name (full name) [Some-State]:.
# Locality Name (eg, city) []:
# Organization Name (eg, company) [Internet Widgits Pty Ltd]:MySQL AB
# Organizational Unit Name (eg, section) []:
# Common Name (eg, YOUR name) []:MySQL user
# Email Address []:
#
# Please enter the following 'extra' attributes
# to be sent with your certificate request
# A challenge password []:
# An optional company name []:

#
# Remove a passphrase from the key (optional)
#
openssl rsa -in $DIR/client-key.pem -out $DIR/client-key.pem

#
# Sign client cert
#

openssl ca  -policy policy_anything -out $DIR/client-cert.pem \
    -config $DIR/openssl.cnf -infiles $DIR/client-req.pem

# Saída exemplo:
# Using configuration from /home/monty/openssl/openssl.cnf
# Enter PEM pass phrase:
# Check that the request matches the signature
# Signature ok
# The Subjects Distinguished Name is as follows
# countryName           :PRINTABLE:'FI'
# organizationName      :PRINTABLE:'MySQL AB'
# commonName            :PRINTABLE:'MySQL user'
# Certificate is to be certified until Sep 13 16:45:17 2003 GMT (365 days)
# Sign the certificate? [y/n]:y
#
#
# 1 out of 1 certificate requests certified, commit? [y/n]y
# Write out database with 1 new entries
# Data Base Updated

#
# Create a my.cnf file that you can use to test the certificates
#

cnf=""
cnf="$cnf [client]"
cnf="$cnf ssl-ca=$DIR/cacert.pem"
cnf="$cnf ssl-cert=$DIR/client-cert.pem"
cnf="$cnf ssl-key=$DIR/client-key.pem"
cnf="$cnf [mysqld]"
cnf="$cnf ssl-ca=$DIR/cacert.pem"
cnf="$cnf ssl-cert=$DIR/server-cert.pem"
cnf="$cnf ssl-key=$DIR/server-key.pem"
echo $cnf | replace " " '
' > $DIR/my.cnf

#
# To test MySQL

mysqld --defaults-file=$DIR/my.cnf &

mysql --defaults-file=$DIR/my.cnf

Você também pode testar sua configuração modificando o arquivo my.cnf acima para fazer referência aos certificados de demonstração no diretório mysql-dist-fonte/SSL.